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Synthesis and transformations of metallacycles. 31. Catalysts based on cobalt complexes in reactions of trialkyl- and alkylhaloalanes with olefins,allenes, and acetylenes
Authors:Ibragimov  A G  Khafizova  L O  Gil"fanova  G N  Yakupova  L R  Borisova  A L  Dzhemilev  U M
Institution:(1) Institute of Petrochemistry and Catalysis, Academy of Sciences of the Bashkortostan Republic and Ufa Scientific Center of the Russian Academy of Sciences, 141 prosp. Oktyabrya, 450075 Ufa, Russian Federation
Abstract:Cobalt-containing complexes capable of catalyzing reactions of trialkyl- and alkylhaloalanes (R n AlCl3–n ) with olefins, allenes, and acetylenes were synthesized. The reactions afford cyclic and acyclic organoaluminum compounds.
Keywords:catalysis  hydro-  cyclo-  carbo-  and dialumination  organoaluminum compounds  olefins  cobalt complexes  deuterolysis
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