Synthesis and transformations of metallacycles. 31. Catalysts based on cobalt complexes in reactions of trialkyl- and alkylhaloalanes with olefins,allenes, and acetylenes
(1) Institute of Petrochemistry and Catalysis, Academy of Sciences of the Bashkortostan Republic and Ufa Scientific Center of the Russian Academy of Sciences, 141 prosp. Oktyabrya, 450075 Ufa, Russian Federation
Abstract:
Cobalt-containing complexes capable of catalyzing reactions of trialkyl- and alkylhaloalanes (RnAlCl3–n) with olefins, allenes, and acetylenes were synthesized. The reactions afford cyclic and acyclic organoaluminum compounds.