Thermotropic polyesters. 2: Synthesis, characterization and thermal transitions of copolyesters containing 4,4′-bis (ω-alkyloxy) biphenyl isophthalate units |
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Authors: | Massoumeh Bagheri Khadije Didehban Ali Akbar Entezami |
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Institution: | a Department of Chemistry, Faculty of Science, Azerbaidjan University of Tarbiat Moallem, Tabriz 5375171379, Iran b Polymer Laboratory, Chemistry Faculty, Tabriz University, Tabriz, Iran |
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Abstract: | Thermotropic copolyesters containing an isophthalate unit and mesogenic 4, 4′-bis (ω-hydroxyalkyloxy) biphenyls (n = 3, 4, 6) with different numbers of methylene units have been synthesized by melt polymerization. The number-average molar mass (Mn) was estimated from end group analysis by 1H NMR. The copolymer compositions were also obtained from 1H NMR. The thermal behavior of the copolymers containing even-even (n = 4, 6) and odd-even (n = 3, 4) pairings has been investigated and is also compared with that of the analogous homopolymers. The copolymers exhibit reduced melting point and extending liquid crystalline range identified using polarizing microscopy and DSC. All of the obtained compounds were characterized by conventional spectroscopic methods. |
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Keywords: | Liquid crystals Thermotropic copolyesters Optical texture DSC Isophthalate |
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