1,8-Diazabicyclo[5.4.0]undec-7-ene (DBU) as ligand for atom transfer radical polymerization (ATRP) |
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Authors: | David Fournier Véronique Montembault |
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Institution: | Université du Maine, LCOM, Chimie des Polymères, UCO2M-UMR CNRS 6011, Avenue O. Messiaen, 72085 Le Mans Cedex 9, France |
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Abstract: | 1,8-Diazabicyclo5.4.0]undec-7-ene (DBU) has been used as a bidentate ligand of copper (I) bromide for the ATRP of (meth)acrylates and styrene. With methyl methacrylate, the polymerization reached high conversions producing polymers with a good control of Mn and low polydispersity indexes (PDI = 1.19). Higher PDI were obtained with polystyrenes and poly(methyl acrylate)s. These results have been correlated to the redox properties of the catalytic complex. |
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Keywords: | Atom transfer radical polymerization (ATRP) Copper complex DBU Electrochemistry Nitrogen bidentate ligand |
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