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Application of the essential work of fracture concept to nanostructured polymer materials
Authors:R. Lach  K. Schneider  A. Janke
Affiliation:a Leibniz Institute of Polymer Research, Mechanics and Fibre Formation, Hohe Strasse 6, 01069 Dresden, Germany
b BASF AG, Polymer Research Thermoplastics, GKT/I-B1, D-67056 Ludwigshafen, Germany
Abstract:The first part of the paper deals with a critical discussion of the methodical basis of essential work of fracture (EWF) concept with respect to the specimen geometry (especially the notch depth) and application to polymers. In the second part, an in situ testing device, which combines a tensile testing machine with an optical strain-field measuring system, has successfully demonstrated possibility of characterization of fracture behaviour of polystyrene-polybutadiene block copolymers and block copolymer/homopolymer blends as examples of nanostructured polymer materials. It has been shown that knowledge of the time evolution of the strain field close to the crack tips leads to a simple verification of the basic precondition for the applicability of the EWF concept, the precondition “plastic zone coalescence-before-stable crack propagation”.
Keywords:CA, cellulose acetate   EPR, ethylene-propylene random copolymer   HIPS, high-impact polystyrene   LLDPE, linear low-density polyethylene   PA, polyamide   PB, polybutadiene   PBT, polybutylene terephthalate   PC, polycarbonate   PEEK, poly(ether-ether ketone)   PEI, polyetherimide   PEN, polyethylene naphthalate   PET, polyethylene terephthalate   PETG, polyethylene terephthalate glycol   PI, polyimide   PPE, poly(phenylene ether)   PP, polypropylene   PS, polystyrene
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