A chiral 6-membered N-heterocyclic carbene copper(I) complex that induces high stereoselectivity |
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| Authors: | Park Jin Kyoon Lackey Hershel H Rexford Matthew D Kovnir Kirill Shatruk Michael McQuade D Tyler |
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| Affiliation: | Department of Chemistry & Biochemistry, Florida State University, Tallahassee, Florida 32306-4390, United States. |
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| Abstract: | A chiral 6-membered annulated N-heterocyclic (6-NHC) copper complex that catalyzes β-borylations with high yield and enantioselectivity was developed. The chiral 6-NHC copper complex is easy to prepare on the gram scale and is very active, showing 10,000 turnovers at 0.01 mol % of catalyst without significant decrease of enantioselectivity and with useful reaction rates. |
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