Polarization Dependence of a Hydrophobized Electrode for Electrosynthesis of a Soluble Product |
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| Authors: | Saltykov Yu V Kornienko V L |
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| Institution: | (1) Institute of Chemistry and Chemical Technology, Siberian Division, Russian Academy of Sciences, ul. K. Marksa 42, Krasnoyarsk, 660049, Russia |
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| Abstract: | An equation for a polarization curve of a hydrophobized electrode is proposed for electrosynthesis of a soluble electroactive product in an inner-kinetic mode. The equation contains the concentration of the target product (TP) in an explicit form. The shape of the curve depends on the biquadratic root of the TP concentration and the square root of the ratio between exchange currents of the side and target reactions. |
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| Keywords: | porous hydrophobized electrode electrosynthesis polarization curve electrochemical activity of product |
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