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Synthesis and primary biological evaluation of 188ReN-NEMPTDD
Authors:Guan-Quan Wang  Ji Zhang  Shun-Zhong Luo  Na Wang  Hong-Yuan Wei  Wen-Jin Wang  Yu-Qing Yang  Guo-Ping Liu  Xiao-Qi Yu
Institution:(1) School of Chemistry and Chemical Engineering, Shandong University, Jinan, 250100, P.R. China;(2) Qilu Hospital, Shandong University, Jinan, 250100, P.R. China
Abstract:The recovery of uranium(VI) from chloride solution using a liquid emulsion membrane (LEM) technique was studied. The emulsion is constituted by the quaternary salt of benzyloctadecyldimethyl ammonium chloride (BODMAC, R4NCl) as a carrier, kerosene as organic diluent, Span 80 as emulsifying agent and 0.5 mol/l Na2CO3 as stripping phase. The important variables affecting the LEM permeation process such as the concentrations of extractant, internal strip phase, types of organic diluent, and the presence of magnesium chloride or magnesium sulfate were investigated. It was found that, at a given condition, the maximum extraction rate of uranium(VI) reached 80%. The emulsion was stable at low pH in the presence of certain amounts of electrolytes such as NaCl and MgCl2.
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