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Effects of organoclays on the thermal processing of pe/clay nanocomposites
Authors:E M Araújo  Renata Barbosa  Crislene R S Morais  L E B Soledade  A G Souza  Moema Q Vieira
Institution:1.Departmento de Engenharia de Materiais,Universidade Federal de Campina Grande,PB,Brazil;2.Departmento de Química, CCEN,Universidade Federal da Paraíba,PB,Brazil;3.Centro de Microscopia Eletr?nica,UFRGS,UFRGS,Brazil
Abstract:Nanocomposites containing both polyethylene and montmorillonite clay organically modified with four different types of quaternary ammonium salts were obtained via direct melt intercalation. Thus, the main purpose of this work was to evaluate the effect of the organoclay on the thermal stability of polyethylene. The organoclays were characterized by XRD, FTIR, DSC and TG. The polyethylene/organoclay nanocomposites were studied by XRD, TEM, TG, besides an evaluation of their mechanical properties. The results showed that the salts were incorporated by intercalation between the layers of the organoclay and, apparently that the nanocomposites were more thermally stable than pure polyethylene.
Keywords:nanocomposite  organoclay  polyethylene  thermal stability
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