An unexpected mechanism of hydrosilylation by a silyl hydride complex of molybdenum |
| |
| Authors: | Khalimon Andrey Y Ignatov Stanislav K Simionescu Razvan Kuzmina Lyudmila G Howard Judith A K Nikonov Georgii I |
| |
| Institution: | Chemistry Department, Brock University, 500 Glenridge Avenue, St. Catharines, Ontario L2S 3A1, Canada. |
| |
| Abstract: | Carbonyl hydrosilylation catalyzed by (ArN)Mo(H)(SiH(2)Ph)(PMe(3))(3) (3) is unusual in that it does not involve the expected Si-O elimination from intermediate (ArN)Mo(SiH(2)Ph)(O(i)Pr)(PMe(3))(2) (7). Instead, 7 reversibly transfers β-CH hydrogen from the alkoxide ligand to metal. |
| |
| Keywords: | |
| 本文献已被 PubMed 等数据库收录！ |
|
