Structure and O2-reactivity of copper(I) complexes supported by pyridylalkylamine ligands |
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| Authors: | Itoh Shinobu Tachi Yoshimitsu |
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| Institution: | Department of Chemistry, Graduate School of Science, Osaka City University, 3-3-138 Sugimoto, Osaka, 558-8585, Japan. shinobu@sci.osaka-cu.ac.jp |
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| Abstract: | The structure and O2-reactivity of a series of copper(I) complexes supported by the pyridylalkylamine ligands are summarized, and the ligand effects such as the chelate ring size effect (five- vs. six-membered ring), the denticity effect (tetradentate vs. tridentate vs. didentate), the steric effect of 6-methylpyridine and the steric and/or electronic effects of N-alkyl substituents are discussed in detail. |
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