| N-杂环卡宾的反应及应用 |
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| 引用本文： | 柳清湘,李正名.N-杂环卡宾的反应及应用[J].化学通报,2004,67(10):715-722,749. |
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| 作者姓名： | 柳清湘 李正名 |
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| 作者单位： | 南开大学国家元素有机化学重点实验室 南开大学农药国家工程中心,天津,300071;中国工程院院士 |
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| 基金项目： | 南开大学人事处科研启动经费资助项目 (P0 2 0 16 ) |
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| 摘 要： | 自从1991年Arduengo第一次分离得到稳定的游离N-杂环卡宾以后，N-杂环卡宾金属络合物的研究在近几年来得到了迅速的发展。N-杂环卡宾的反应性能较高，它们与周期表中几乎所有的元素都能发生反应。N-杂环卡宾金属络合物对许多反应有催化作用，它们是一类有潜在应用价值的催化剂。本文对近年来相关的研究成果进行了综述。
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| 关 键 词： | N-杂环卡宾 金属络合物 催化剂 |
Reaction and Application of N-Heterocyclic Carbene |
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| Liu Qingxiang,Li Zhengming #.Reaction and Application of N-Heterocyclic Carbene[J].Chemistry,2004,67(10):715-722,749. |
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| Authors: | Liu Qingxiang Li Zhengming # |
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| Abstract: | Since first free N-heterocyclic carbene was isolated by Ardengo in 1991, the study of N-heterocyclic carbene metal complexes has reached a fast development in recent years. Because N-heterocyclic carbene has very high activity of reaction, it can react with all elements in periodical table. N-heterocyclic carbene metal complexes have catalytic activities for many organic reactions, and they are a type of catalyst with potential value. In this paper, the recent results of research relating to this type of carbenes are reviewed. |
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| Keywords: | N-heterocyclic carbene Metal complexes Catalyst |
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