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Triterpene Glycosides of Astragalus and Their Genins. LXVII. Structure of Cycloexoside B
Authors:R P Mamedova  M A Agzamova  M I Isaev
Institution:(1) S. Yu. Yunusov Institute of the Chemistry of Plant Substances, Academy of Sciences of the Republic of Uzbekistan, Tashkent
Abstract:Another seven components from the roots of Astragalus exilis A.Kor. (Leguminosae) were identified using spectral data and chemical transformations. A triterpenoid of genin nature was identical to cyclosiversigenin. One compound of glycosidic nature turned out to be a new cycloartane glycoside called by us cycloexoside B of structure 20R,24S-epoxycycloartan-3beta,6agr,16beta,25-tetraol 3-O-beta-D-(2-Oacetyl) xylopyranoside. Five glycosides were identified as cyclosiversigenin 3-O-beta-D-xylopyranoside and cyclosiversiosides B, C, D, and G.
Keywords:triterpenoids  cycloartanes  cyclosiversigenin  cycloexoside B  cyclosiversiosides  Astragalus  Leguminosae  PMR  13NMR  DEPT  J-modulation
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