Allylpalladium umpolung in the three-component coupling synthesis of homoallylic amines |
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Authors: | Hopkins Chad D Malinakova Helena C |
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Affiliation: | Department of Chemistry, University of Kansas, 1251 Wescoe Hall Drive, Lawrence, Kansas 66045-7582, USA. |
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Abstract: | [Structure: see text] Homoallylic amines and alpha-amino esters were prepared via a Pd(II)-catalyzed coupling of boronic acids and 1,2-nonadiene with ethyl iminoacetate or aliphatic, aromatic, and heteroaromatic imines. The allylpalladium umpolung was induced by a Pd(OAc)2 catalyst with commercial phosphine ligands. |
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