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Enantioselective reduction of 2-substituted tetrahydropyran-4-ones using Daucus carota plant cells |
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| Authors: | J.S. Yadav B.V. Subba Reddy Ch. Sreelakshmi G.G.K.S. Narayana Kumar A. Bhaskar Rao |
| Affiliation: | Division of Organic Chemistry, Indian Institute of Chemical Technology, Hyderabad 500 007, India |
| Abstract: | Enzymatic reduction of 2-substituted tetrahydropyran-4-ones with Daucus carota, plant cells as biocatalyst occurred in water under extremely mild and environmentally benign conditions giving a 1:1 mixture of diastereoselectively (2R,4S)- and (2S,4S)-2-aryl- or 2-alkyl-tetrahydropyranols in high yields. |
| Keywords: | Biocatalytic transformation Carrot root Enantioselective reduction Chiral tetrahydropyranols |
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