Enantioselective Henry reaction catalyzed by trianglamine-Cu(OAc)2 complex under solvent-free conditions |
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Authors: | Koichi Tanaka Satoshi Hachiken |
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Institution: | Department of Chemistry and Materials Engineering, Faculty of Chemistry, Materials and Bioengineering & High-Tech Research Centre, Kansai University, Suita, Osaka 564-8680, Japan |
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Abstract: | Chiral trianglamine-Cu(OAc)2 complex was found to be an efficient catalyst for enantioselective Henry reaction between nitromethane and various aldehydes to provide β-hydroxynitoroalkanes with high enantiomeric excesses under solvent-free conditions. |
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