Synthesis and Fluorescence Properties of Lanthanide (III) Perchlorate Complexes with Naphthyl-Naphthalinesulphonylpropyl Sulfoxide |
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Authors: | Wen-Xian Li Yu-Shan Zheng Xiao-Jun Sun Xiao-Yan Shi Wen-Juan Chai and Tie Ren |
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Institution: | (1) College of Chemistry and Chemical Engineering, Inner Mongolia University, Hohhot, 010021, People’s Republic of China;(2) Inner Mongolia Autonomous Region Product Quality Supervision and Inspection Institute, Hohhot, 010010, People’s Republic of China |
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Abstract: | A ligand with double sulfinyl groups, naphthyl-naphthalinesulphonylpropyl sulfoxide(dinaphthyl disulfoxide, L), was synthesized
by a new method and its several lanthanide (III) complexes were synthesized and characterized by element analysis, molar conductivity,
coordination titration analysis, IR, TG-DTA, 1HNMR and UV spectra. The composition of these complexes, were RE2(ClO4)6·(L)5·nH2O (RE = La, Nd, Eu, Tb, Yb, n = 2 ∼ 6, L = C10H7SOC3H6SOC10H7). The fluorescent spectra illustrated that the Eu (III) complex had an excellent luminescence. It was supposed that the ligand
was benefited for transferring the energy from ligand to the excitation state energy level (5D0) of Eu (III). The Tb (III) complex displayed weak luminescence, which attributed to low energy transferring efficiency between
the average triplet state energy level of ligand and the excited state (5D4) of Tb (III). So the Eu (III) complex displayed a good antenna effect for luminescence. The phosphorescence spectra and the
relationship between fluorescence lifetime and fluorescence intensity were also discussed. |
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