A novel four-coordinate zinc(II) complex of the di-N-hydroxypropylated tetraaza macrocycle |
| |
| Authors: | Ki-Young Choi Yong-Man Jeon Choon Pyo Hong Haiil Ryu Il-Hwan Suh |
| |
| Affiliation: | (1) Department of Cultural Heritage Conservation Science, Kongju National University, Kongju, 314-701, South Korea;(2) Taejon Daeshin High School, Taejon, 302-210, South Korea;(3) Department of Chemical Education, Kongju National University, Kongju, 314-701, South Korea;(4) Department of Physics, Chungnam National University, Taejon, 305-764, South Korea |
| |
| Abstract: | The compound [Zn(L2)Cl]ClO4·H2O (1) (L2 = 2,13,-bis(3-hydroxypropyl)-5,16-di-methyl-2,6,13,17-tetraazatricyclo[14,4,01.18,07.12]docosane) has been synthesized and structurally characterized. 1 crystallizes in the monoclinic system, space group P21/c with a = 8.932(2), b = 16.189(2), c = 22.492(4) Å  = 95.34(2)° V = 3238.3(11) Å3; and Z = 4. The zinc atom is placed in a highly distorted tetrahedral environment bonding with three nitrogen atoms of the macrocycle and one chlorine atom. |
| |
| Keywords: | crystal structure zinc(II) complex 3-hydroxypropyl pendant arm tetraaza macrocycle |
| 本文献已被 SpringerLink 等数据库收录！ |
|
