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新的金属氧化物纳米催化剂CuO-ZnO高效催化醇化学选择性乙酰化(英文)
作者姓名:Jalal Albadi  Amir Alihosseinzadeh  Mehdi Mardani
作者单位:Behbahan Khatam Alanbia University of Technology,Behbahan,Iran;School of Chemical Engineering,University of Tehran,Tehran,Iran
基金项目:the research council of Behbahan Kha-tam Alanbia University of Technology for supporting this work
摘    要:A new method has been developed for the chemoselective acetylation of alcohols with acetic anhy‐dride in the presence of phenols using a novel,recyclable Cu O‐Zn O nanocatalyst.The catalyst was synthesized using the co‐precipitation method and characterized by N2 adsorption‐desorption,X‐ray diffraction,scanning electron microscopy,transmission electron microscopy and energy dis‐persion scanning analyses.Furthermore,this catalyst could be recycled up to six times without significant loss in its activity.

关 键 词:CuO-ZnO  nanocatalyst  Alcohol  Chemoselective  acetylation  Acetic  anhydride

Efficient approach for the chemoselective acetylation of alcohols catalyzed by a novel metal oxide nanocatalyst CuO-ZnO
Jalal Albadi,Amir Alihosseinzadeh,Mehdi Mardani.Efficient approach for the chemoselective acetylation of alcohols catalyzed by a novel metal oxide nanocatalyst CuO-ZnO[J].Chinese Journal of Catalysis,2015(3):308-313.
Authors:Jalal Albadi;Amir Alihosseinzadeh;Mehdi Mardani;Behbahan Khatam Alanbia University of Technology  Behbahan  Iran;
Institution:1. Behbahan Khatam Alanbia University of Technology, Behbahan, Iran;2. School of Chemical Engineering, University of Tehran, Tehran, Iran
Abstract:A new method has been developed for the chemoselective acetylation of alcohols with acetic anhy‐dride in the presence of phenols using a novel, recyclable CuO‐ZnO nanocatalyst. The catalyst was synthesized using the co‐precipitation method and characterized by N2 adsorption‐desorption, X‐ray diffraction, scanning electron microscopy, transmission electron microscopy and energy dis‐persion scanning analyses. Furthermore, this catalyst could be recycled up to six times without significant loss in its activity.
Keywords:CuO-ZnO nanocatalyst  Alcohol  Chemoselective acetylation  Acetic anhydride
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