2,2‐Bis(methoxy‐NNO‐azoxy)ethyl Derivatives of 4,8‐Dihydro‐bis‐furazano[3,4‐b:3′4′‐e]pyrazine: The Synthesis and X‐ray Investigation |
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| Authors: | Igor N. Zyuzin Kyrill Yu. Suponitsky Aleksei B. Sheremetev |
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| Affiliation: | 1. Institute of Problems of Chemical Physics, Russian Academy of Sciences, , Moscow, Region 142432 Russia;2. X‐Ray Structural Centre, A.N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, , Moscow, 117813 Russia;3. N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, , Moscow, 119991 Russia |
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| Abstract: | The first synthesis of 4,8‐dihydro‐bis‐furazano[3,4‐b:3′4′‐e]pyrazine bearing 2,2‐bis(methoxy‐NNO‐azoxy)ethyl groups has been developed. These compounds are obtained by aza‐Michael reaction of 1,1‐bis(methoxy‐NNO‐azoxy)ethene or its equivalents, such as 2,2‐bis(methoxy‐NNO‐azoxy)ethanol derivatives, with 4,8‐dihydro‐bis‐furazano[3,4‐b:3′4′‐e]pyrazine. |
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