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Cesium chromate,Cs2CrO4: heat capacity and thermodynamic properties from 5 to 350 K
Authors:William G. Lyon  Darrell W. Osborne  Howard E. Flotow
Affiliation:Chemistry Division, Argonne National Laboratory, Argonne, Illinois 60439, U.S.A.
Abstract:The heat capacity of a sample of Cs2CrO4 was determined in the temperature range 5 to 350 K by aneroid adiabatic calorimetry. The heat capacity at constant pressure Cpo(298.15 K), the entropy So(298.15 K), the enthalpy {Ho(298.15 K) - Ho(0)} and the function ? {Go(298.15 K) - Ho(0)}298.15K were found to be (146.06 ± 0.15) J K?1 mol?1, (228.59 ± 0.23) J K?1 mol?1, (30161 ± 30) J mol?1, and (127.43 ± 0.13) J K?1 mol?1, respectively. The heat capacity Cpo(298.15 K) and entropy So(298.15 K) and entropy So(298.15 K) of Rb2CrO4 are estimated to be (146.0 ± 1.0) J K?1 mol?1 and (217.6 ± 3.0) J K?1 mol?1, respectively.
Keywords:To whom correspondence concerning this paper should be directed.
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