On the character of molecular weight distribution of polyethylene produced in the presence of the homogeneous catalytic system (C5H5)2TiCl2Al(C2H5)2Cl |
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Authors: | A.B. Agasaryan G.P. Belov S.P. Davtyan M.L. Eritsyan |
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Affiliation: | Branch of the Institute of Chemical Physics, USSR Academy of Sciences, Chernogolovka, Moscow Region, 142432, U.S.S.R. |
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Abstract: | Experimental results obtained when studying the kinetics of ethylene polymerization in toluene, as well as data on fractionating polyethylene, are analysed and compared with the results of theoretical consideration of molecular weight distribution on the basis of the proposed kinetic scheme.The constants of the reactions of propagation, initiation, transfer and termination of polymer chains are evaluated and compared with literature data. |
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Keywords: | To whom correspondence should be addressed. |
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