Infrared band intensities and bond polarities: Part 5 - XCl4 molecules (X = C,Si, Ge,Sn)期刊界 All Journals 搜尽天下杂志传播学术成果专业期刊搜索期刊信息化学术搜索

Infrared band intensities and bond polarities: Part 5 - XCl4 molecules (X = C,Si, Ge,Sn)

Authors:	Helen Stoeckli-Evans A.J. Barnes W.J. Orville-Thomas

Affiliation:	Department of Chemistry and Applied Chemistry, University of Salford, Salford M5 4WT Great Britain

Abstract:	Gas phase band intensities of v₃ and v₄ of SiCl₄, GeCl₄ and SnCl₄ have been derived from dispersion curves measured using a Michelson interferometer in the range 1000 to 10 cm^?1. The results obtained are discussed in relation to the corresponding liquid phase band intensities. Bond polar properties are derived from the observed intensities using a modified Gribov method, the moments obtained being 0.9 D for SiCl, 1.5 D for GeCl and 2.7 D for SnCl.

Keywords:	Present address: Institut de Chimie Université de Neuchatel Neuchatel Switzerland.
本文献已被 ScienceDirect 等数据库收录！