First‐principles calculations on thermodynamic properties of BaTiO3 rhombohedral phase |
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Authors: | Andrei V Bandura Robert A Evarestov |
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Institution: | Department of Chemistry, Quantum Chemistry Division, St. Petersburg State University, Universitetsky Prosp. 26, 198504 St. Petersburg, Petergof, Russia |
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Abstract: | The calculations based on the linear combination of atomic orbitals have been performed for the low‐temperature phase of BaTiO3 crystal. Structural and electronic properties, as well as phonon frequencies were obtained using hybrid PBE0 exchange–correlation functional. The calculated frequencies and total energies at different volumes have been used to determine the equation of state and thermal contribution to the Helmholtz free energy within the quasiharmonic approximation. For the first time, the bulk modulus, volume thermal expansion coefficient, heat capacity, and Grüneisen parameters in BaTiO3 rhombohedral phase have been estimated at zero pressure and temperatures form 0 to 200 K, based on the results of first‐principles calculations. Empirical equation has been proposed to reproduce the temperature dependence of the calculated quantities. The agreement between the theoretical and experimental thermodynamic properties was found to be satisfactory. © 2012 Wiley Periodicals, Inc. |
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Keywords: | hybrid DFT calculations perovskite polymorphs phonon frequencies thermal free energy bulk modulus heat capacity thermal expansion Grü neisen parameter |
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