Octanuclear Cu(I)‐dithiophosphates: An Efficient Catalyst System for N‐Arylation of Azoles,Amines, and Amides |
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| Authors: | Cheng‐Chieh Wu Bo‐Han Lee Ping‐Kuei Liao Ching‐Shiang Fang C. W. Liu |
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| Affiliation: | Department of Chemistry, National Dong Hwa University, Hualien, Taiwan 97401, R.O.C. |
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| Abstract: | The formation of a C‐N bond via the cross‐couplings of aryl iodides with azoles, aryl amine, and amides can be successfully achieved in decent yield by the utilization of both [Cu 8(H){S2P(OiPr)2}6]+ and [Cu8{S2P(OEt)2}6]2+ as the pre‐catalysts. |
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| Keywords: | Copper S‐donor ligands N‐arylation Cross‐coupling |
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