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Rotational transitions in degenerate vibrational states of C3v symmetric top molecules,with application to CH3C15N
Authors:A.J. Careless  H.W. Kroto
Affiliation:School of Molecular Sciences, University of Sussex, Brighton BN1 9QJ UK
Abstract:General algebraic expressions for the vibration-rotation energy levels and the associated rotational transitions of C3v symmetric top molecules are developed. These expressions are presented in a convenient form for analysing the spectra of a molecule with any degree of excitation of a degenerate vibrational mode and have been applied to the spectrum of CH3C15N.
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