| Synthesis and Structure of a Novel Copper（Ⅱ） Dinuclear Complex with 4,4′-Dipyridyl as the Bridge |
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| 引用本文： | 刘小兰,赵茹,刘晓红,岳俊杰,尹宇新,孙云,张欣.Synthesis and Structure of a Novel Copper（Ⅱ） Dinuclear Complex with 4,4′-Dipyridyl as the Bridge[J].中国化学,2003,21(8):1047-1053. |
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| 作者姓名： | 刘小兰 赵茹 刘晓红 岳俊杰 尹宇新 孙云 张欣 |
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| 作者单位： | [1]CollegeofChemistryandLifeScience,TianjinNormalUniversity,Tianjin300074,China [2]NavalLogisticsInstitute,TianjinTanggu300054,China [3]KeyLaboratoryofBioorganicPhosphorousChemistry,DepartmentofChemistry,TsinghuaUniversity,Beijing100084,China |
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| 摘 要： | With N,N′-bis(benzimidazol-2-methyl)amine as the ligand,a novel Cu(Ⅱ) dinuclear complex was synthesized as a mimetic compound of superoxide dismutase(SOD).The complex was characterized with element analysis,UV and IR spectra.The crystal structure was determined by using X-ray diffraction analysis.the crystal structure shows that Cu(Ⅱ) and its coordinated atoms construct distorted octahedron configuration with oxygen atome of (ClO4-)s in the axial directions.The coordinated cations are linked by (ClO4-)s to form nonplanar sheets.All sheets are linked together into three-dimensional network by the intermolecular hydrogen bonds.The result of the activity assay indicates that the complex does have certain biological activity.
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| 关 键 词： | 合成 晶体结构 铜双核配合物 Cu（Ⅱ） 4 4′-联吡啶 桥键 N-N′-双（苯并咪唑-2-甲基）胺 三维空间网状配合物 生物活性 |
Synthesis and Structure of a Novel Copper (II) Dinuclear Complex with 4,4′‐Dipyridyl as the Bridge |
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| Liu Xiao‐Lan,Zhao Ru,Liu Xiao‐Hong,Yue Jun‐Jie,Yin Yu‐Xin,Sun Yun Zhang.Synthesis and Structure of a Novel Copper (II) Dinuclear Complex with 4,4′‐Dipyridyl as the Bridge[J].Chinese Journal of Chemistry,2003,21(8):1047-1053. |
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| Authors: | Liu Xiao‐Lan Zhao Ru Liu Xiao‐Hong Yue Jun‐Jie Yin Yu‐Xin Sun Yun Zhang |
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