Nickel-catalyzed [4+2] cycloaddition for highly substituted arenes |
| |
| Authors: | Horie Hiroaki Kurahashi Takuya Matsubara Seijiro |
| |
| Affiliation: | Department of Material Chemistry, Graduate School of Engineering, Kyoto University, Kyoto 615-8510, Japan. |
| |
| Abstract: | Nickel(0) catalyzed [4+2] cycloaddition of electron-deficient dienes to alkynes and subsequent aromatization gave highly substituted arenes. This formal inverse electron-demand Diels-Alder cycloaddition is attributed to the formation of a seven-membered nickelacycle from a diene and an alkyne. |
| |
| Keywords: | |
| 本文献已被 PubMed 等数据库收录！ |
|
