On the thermal fluctuations of free charge in the Ershler-Randles circuit |
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Authors: | B M Grafov |
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Institution: | (1) Karpenko Physico-Mechanical Institute of the NAS of Ukraine, 5, Naukova Str, 79601 Lviv, Ukraine; |
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Abstract: | Noise method for the analyzing of thermodynamic second-order fluctuations of the electrical double layer charge in complicated
electrochemical systems is developed. The method is based on the joint application of the Nyquist fluctuation-dissipation
theorem and Laplace transform. Second-order fluctuations of the free charge in the electrical double layer are studied under
the conditions when the weak-signal faradaic impedance of equilibrated electrode is determined by the diffusion impedance,
alongside with the slow-discharge resistance. It is shown that, unlike the high-order fluctuations, the level of thermodynamic
second-order fluctuations of the free charge does not depend on the mechanism of interaction of the thermodynamic system with
thermostat; it fully corresponds to the conceptions of the Gibbs statistical thermodynamics. |
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Keywords: | |
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