Synthesis and properties of chiral ammonium-based ionic liquids |
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Authors: | Pernak Juliusz Feder-Kubis Joanna |
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Affiliation: | Poznań University of Technology, Department of Chemical Technology pl. Sk?odowskiej-Curie 2, 60-965 Poznań, Poland. juliusz.pernak@put.poznan.pl |
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Abstract: | New chiral ammonium-based ionic liquids containing the (1R,2S,5R)-(-)-menthyl group can be easily and efficiently prepared under ambient conditions. The preparation and characterization of trialkyl[(1R,2S,5R)-(-)-menthoxymethyl]ammonium salts is reported. The salts have been demonstrated to be air- and moisture-stable under ambient conditions and can be readily used in a variety of standard experimental procedures. The single-crystal X-ray structure of butyldimethyl[(1R,2S,5R)-(-)-menthoxymethyl]ammonium chloride has been determined. The chiral, room-temperature ionic liquids have been characterized by physical properties such as specific rotation, density, viscosity, thermal degradation, and glass transition temperature. Trialkyl[(1R,2S,5R)-(-)-menthoxymethyl]ammonium chloride prototype ionic liquids have also been found to exhibit strong antimicrobial and high antielectrostatic activities. |
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Keywords: | ammonium salts antimicrobial activity chirality green chemistry ionic liquids menthol |
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