Superacid Catalyst SO42-/ZrO2-La2O3 Prepared by Ultrasonic Co-precipitation and Low Temperature Aging |
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Authors: | Tong-yun Chen Xiang-feng Chua Ke-liang Hu |
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Affiliation: | School of Chemistry and Chemical Engineering, Anhui University of Technology, Maanshan 243002,China;School of Chemistry and Chemical Engineering, Anhui University of Technology, Maanshan 243002,China;Center of Structure Analysis, University of Science and Technology of China, Hefei 230026, China |
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Abstract: | Sulfated zirconia-lanthana (SO42-/ZrO2-La2O3) precursors were prepared by ultrasonic co-precipitation method and followed by aging at different temperature. The precursors weretreated by 0.5 mol/L H2SO4. Samples of SO42-/ZrO2-La2O3nano-crystalline catalysts wereobtained by baking the treated precursors at different temperatures. The acidic properties ofSO42-/ZrO2-La2O3 were tested by the Hammett indicator method. The phase composition,specific area, particle structure, and surface state were characterized by X-ray diffraction,BET, transmission electron microscopy, infrared spectrum, and X-ray photoelectron spec-troscopy. The catalytic activities were estimated by esterification of acetic acid with glycerin.It was shown that the catalyst prepared by ultrasonic stirring and low temperature (-15 ºC)exhibited highly active sites and high catalytic property. |
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Keywords: | Superacid SO42-/ZrO2-La2O3 Preparation Ultrasonic |
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