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Neue Pyridiniumchlorometallatverbindungen der Seltenerdelemente |
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| Authors: | K. Rossmanith P. Unfried |
| Affiliation: | (1) Institut für Anorganische Chemie, Universität Wien, A-1090 Wien, Österreich |
| Abstract: | Summary Reaction of the rare earth chlorides with pyridinium chloride in tetrahydrofuran (THF) under anhydrous conditions gave nearly insoluble precipitates of the composition (pyH)3RECl6·THF (RE=La, Ce, Pr, Nd, Sm, Eu, Gd, Tb, Dy, Ho, Y, Er, Tm, Yb, and Lu). They were characterized by chemical analysis and IR spectroscopy; decompositionin vacuo was studied, yielding the hithero unknown complexes (pyH)3RECl6 (RE=La, Ce, Pr, Sm, Tb, Ho, Y, Tm, and Lu). |
| Keywords: | Pyridiniumchlorometallates of rare earth elements Rare earth pyridiniumchlorometallateTHF Solvates |
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