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Elution dynamics of adsorption of Chladon 113 and methyl bromide on active carbons
Authors:M L Gubkina  A V Larin  N S Polyakov
Institution:(1) Institute of Physical Chemistry, Russian Academy of Sciences, 31 Leninsky prosp., 117915 Moscow, Russian Federation
Abstract:The elution dynamics of adsorption of Chladon 113 (at high contents of the adsorptive) and methyl bromide on active carbons with different lengths of the layer was studied. The adsorption isotherms were described by the equation of the theory of volume filling of micropores. The elution curves were calculated using the model of the equilibrium adsorption layer. The effective kinetic constant calculated in the framework of the model is 1.5 cm for Chladon 113 at a linear velocity of vapor-air flow of 1250 cm min−1 and 1.0 cm for methyl bromide at the velocity of 700 cm min−1. Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 7, pp. 1353–1355, July, 1998.
Keywords:elution adsorption dynamics  Chladon 113  methyl bromide  elution curves
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