Cooperative catalysis approach to intramolecular hydroacylation |
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| Authors: | Evgeny V Beletskiy Ch Sudheer Christopher J Douglas |
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| Affiliation: | Department of Chemistry, University of Minnesota-Twin Cities, 207 Pleasant Street SE, Minneapolis, Minnesota 55455, USA. |
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| Abstract: | Prior examples of hydroacylation to form six- and seven-membered ring ketones require either embedded chelating groups or other substrate design strategies to circumvent competitive aldehyde decarbonylation. A cooperative catalysis strategy enabled intramolecular hydroacylation of disubstituted alkenes to form seven- and six-membered rings without requiring substrate-embedded chelating groups. |
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