| Preparation and spectroscopic properties of 2'''',5''''-dideoxynucleosidylcobalamins |
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| 引用本文： | YAN,Hong CHEN,Hui-Lan SUN,Hong-Zhe XIE,De-Ping TANG,Wen-XiaDepartment of Chemistry and State Key Laboratory of Coordination Chemistry,Nanjing University,Nanjing,Jiangsu 210008,China. Preparation and spectroscopic properties of 2'''',5''''-dideoxynucleosidylcobalamins[J]. 中国化学, 1994, 0(1) |
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| 作者姓名： | YAN Hong CHEN Hui-Lan SUN Hong-Zhe XIE De-Ping TANG Wen-XiaDepartment of Chemistry and State Key Laboratory of Coordination Chemistry Nanjing University Nanjing Jiangsu 210008 China |
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| 作者单位： | YAN，Hong CHEN，Hui-Lan SUN，Hong-Zhe XIE，De-Ping TANG，Wen-XiaDepartment of Chemistry and State Key Laboratory of Coordination Chemistry，Nanjing University，Nanjing，Jiangsu 210008，China |
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| 基金项目： | Project supported by the National Natural Science Foundation of China. |
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| 摘 要： | Two new coenzyme B12 analogues, 2',5'-dideoxycytidylcobalamin (2a) and 2',5'-dide-oxyuridinylcobalamin (2b), and two others, 2',5'-dideoxyadenosylcobalamin (2c), and 5'-deoxy-thymidylcobalamin (2d) were prepared by an improved method. All the four analogues were investigated by UV-vis and 2D 1H NMR spectroscopy. The comparisons and discussion about their spectroscopic properties were done.
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Preparation and spectroscopic properties of 2'''',5''''-dideoxynucleosidylcobalamins |
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| YAN,Hong CHEN,Hui-Lan SUN,Hong-Zhe XIE,De-Ping TANG,Wen-Xia. Preparation and spectroscopic properties of 2'''',5''''-dideoxynucleosidylcobalamins[J]. Chinese Journal of Chemistry, 1994, 0(1) |
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| Authors: | YAN Hong CHEN Hui-Lan SUN Hong-Zhe XIE De-Ping TANG Wen-Xia |
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| Affiliation: | YAN,Hong CHEN,Hui-Lan SUN,Hong-Zhe XIE,De-Ping TANG,Wen-XiaDepartment of Chemistry and State Key Laboratory of Coordination Chemistry,Nanjing University,Nanjing,Jiangsu 210008,China |
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| Abstract: | Two new coenzyme B12 analogues, 2',5'-dideoxycytidylcobalamin (2a) and 2',5'-dide-oxyuridinylcobalamin (2b), and two others, 2',5'-dideoxyadenosylcobalamin (2c), and 5'-deoxy-thymidylcobalamin (2d) were prepared by an improved method. All the four analogues were investigated by UV-vis and 2D 1H NMR spectroscopy. The comparisons and discussion about their spectroscopic properties were done. |
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| Keywords: | Coenzyme B12 analogues cobalamin 2'-deoxynucleoside UV-vis spectra 2D 1H NMR. |
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