Novel 3D metal-organic framework with Prussian Blue topology: [Mn(HCOO)3]n·xnH2O |
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| Authors: | C Zhou Y Li J Guo P Yang |
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| Institution: | (1) Institute of Molecular Science, Shanxi University, China;(2) College of Chemistry and Chemical Engineering, Shanxi University, China |
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| Abstract: | A novel complex, Mn(HCOO)3]n·xnH2O, has been synthesized and studied by X-ray crystallography. The structure is trigonal, space group R-3c, a = 8.327(1) Å, c = 22.890(6) Å, V = 1374.4(5) Å3, Z = 6; final R = 0.045. The crystal structure reveals both O-atoms of the formic acid ligand coordinated to Mn(III) to form a three-dimensional porous framework with the topology of Prussian Blue. |
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| Keywords: | coordination polymer three-dimensional framework porous structure manganese(III) |
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