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Phosphorescence of aromatic molecules in complexes with crystalline β-cyclodextrin at room temperature
Authors:V B Nazarov  V I Gerko  M V Alfimov
Institution:(1) Institute of Chemical Physics in Chernogolovka, Russian Academy of Sciences, 142432 Chernogolovka, Moscow Region, Russian Federation
Abstract:The rate constants for the quenching by oxygen of triplet states of aromatic molecules (naphthalenes-d8 and-h8, phenanthrene) forming inclusion complexes with crystalline β-cyclodextrin in water at 290 K are equal to 900–1300 L mol−1s−1. Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 8, pp. 1450–1453, August, 1997.
Keywords:phosphorescence  triplet state  lifetime  quenching  oxygen  naphthalene  phenanthrene  microcrystal  inclusion complex
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