Epoxidation with an electrocatalytic p-450 model system in an acidic solution |
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| Authors: | Michida Takashi Saiki Chika Yamasaki Chie Yamaoka Yumiko |
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| Affiliation: | Faculty of Pharmaceutical Sciences, Kobe-Gakuin University, Kobe, Japan. michida@pharm.kobegakuin.ac.jp |
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| Abstract: | An electrochemical P-450 model system using meso-tetraphenylporphyrinatomanganese(III) chloride (MnTPP), imidazole and acetic acid was tested in an acetonitrile solution, and epoxide was obtained with a good current efficiency. The results of cyclic voltammetry revealed that acid plays an important role in the second electron transfer. |
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