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| 固相熔融合成含4,4'-联吡啶二阳离子的哑铃型化合物 | |
| 引用本文： | 齐建永,张青丽,许新华,黎小武,贺干武,王炳清,卢锐亮,方敬坤.固相熔融合成含4,4'-联吡啶二阳离子的哑铃型化合物[J].有机化学,2006,26(4):556-558. |
| 作者姓名： | 齐建永 张青丽 许新华 黎小武 贺干武 王炳清 卢锐亮 方敬坤 |
| 作者单位： | 1. 湖南大学化学化工学院,长沙,410082 2. 湖南大学化学化工学院,长沙,410082;邵阳学院化学系,邵阳,422400 3. 湖南大学化学化工学院,长沙,410082;新疆吐鲁番地区实验中学,吐鲁番,838000 |
| 基金项目： | 国家自然科学基金(No.20372020)资助项目 |
| 摘 要： | 2-{2-4-苯基-二(4-特丁基苯基)甲基]苯氧基}乙氧乙醇磺酸酯(2.1 mmol)与4,4'-联吡啶(1.0 mmol)混合, 加热到融化, 搅拌10 min, 用石油醚洗涤反应混合物, 得到定量的哑铃型化合物. |
| 关 键 词： | 无溶剂 无催化剂 固相融溶 合成 哑铃型化合物 |
| 收稿时间： | 04 6 2005 12:00AM |
| 修稿时间： | 08 9 2005 12:00AM |
Synthesis of Dumbbell-Shape Compound Contain-ing4,4'-Bipyridinium Dication under Solid Phase Fusion |
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| QI,Jian-Yong,ZHANG,Qing-Li,XU,Xin-Hua,LI,Xiao-Wu,HE,Gan-Wu,WANG,Bing-Qing,LU,Rui-Liang,FANG,Jing-Kun.Synthesis of Dumbbell-Shape Compound Contain-ing4,4''-Bipyridinium Dication under Solid Phase Fusion[J].Chinese Journal of Organic Chemistry,2006,26(4):556-558. | |
| Authors: | QI Jian-Yong ZHANG Qing-Li XU Xin-Hua LI Xiao-Wu HE Gan-Wu WANG Bing-Qing LU Rui-Liang FANG Jing-Kun |
| Institution: | 1.College of Chemistry and Chemical Engineering, Hunan University, Changsha 410082;2.Department of Chemistry, Shaoyang University, Shaoyang 422400;3.Tulufan District High School, Tulufan 838000 |
| Abstract: | The mixture of tosylate of 2-{2-{4-1-phenyl-1,1'-bis(4-tert-butylphenyl)methyl]phenoxy}eth- oxy}ethanol and 4,4'-bipyridine was heated to melt for 10 min, then washed with petroleum. The dumb- bell-shape compound containing 4,4'-bipyridinium dication was yielded quantitatively. |
| Keywords: | solvent-free uncatalyst solid phase fusion synthesis dumbbell-shape compound |
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