Enantioselective conjugate addition of phenylboronic acid to enones catalysed by a chiral tropos/atropos rhodium complex at the coalescence temperature |
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| Authors: | Monti Chiara Gennari Cesare Piarulli Umberto |
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| Affiliation: | Dipartimento di Chimica Organica e Industriale, Centro di Eccellenza C. I. S. I., Università degli Studi di Milano, Istituto di Scienze e Tecnologie Molecolari (ISTM) del CNR, Via G. Venezian 21, Milan 20133, Italy. |
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| Abstract: | A highly enantioselective rhodium-catalysed conjugate addition of phenylboronic acid to cyclic enones has been achieved using a dynamic library of chiral phosphorus ligands; the tropos/atropos nature of the ligands in the rhodium complex has been characterised via 31P-NMR. |
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