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Effect of alkali metal ions on the intrazeolitic migration of Tb(III) ions in zeolite Y
Authors:Suk Bong Hong  Eun Woo Shin  Sang Heup Moon and Young Sun Uh
Institution:(1) Korea Institute of Science and Technology, Cheongryang, P. O. Box 131, 130-650 Seoul, Korea;(2) Department of Chemical Engineering, Seoul National University, 151-742 Seoul, Korea
Abstract:The luminescence spectra of TbLi-Y, TbNa-Y and TbK-Y zeolites treated at different temperatures are reported. It is found that the intrazeolitic migration temperature of Tb(III) ions to hexagonal prisms is influenced by the type of the alkali metal ion present together with Tb(III) to neutralize the negative framework of zeolite Y.
Keywords:Tb(III)  intrazeolitic migration
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