| 氟两相催化反应的进展 |
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| 引用本文： | 廖永卫,陈卫平. 氟两相催化反应的进展[J]. 有机化学, 2001, 21(3): 181-190 |
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| 作者姓名： | 廖永卫 陈卫平 |
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| 作者单位： | 第二军医大学化学教研室 |
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| 摘 要： | 对氟两相催化反应作一介绍。氟两相体系是一种新的相分离和固定化技术，全氟溶剂与大多数有机溶剂不互溶，而在催化剂分子中引入适当数量、大小和形状的氟尾能使之优先溶于全氟溶剂，在氟两相体系中进行催化反应就使催化剂的回收再用产物的纯化都变得极为方便。
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| 关 键 词： | 氟两相催化反应 非均相反应 催化剂 固定化 相分离 全氟代烃 氟两相体系 |
| 修稿时间： | 2000-08-13 |
Fluorous biphasic catalysis |
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| LIAO Yong Wei ,CHEN Wei Ping. Fluorous biphasic catalysis[J]. Chinese Journal of Organic Chemistry, 2001, 21(3): 181-190 |
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| Authors: | LIAO Yong Wei CHEN Wei Ping |
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| Affiliation: | LIAO Yong Wei *,CHEN Wei Ping |
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| Abstract: | Fluorous biphase system represents a new phase separation and immobilization technique. Perfluorinated solvents have limited miscibility with most of organic solvents. Combined with the fact that compounds functionalized with fluorous ponytails of appropriate number, size, and shape often dissolve preferentially in perfluorinated solvents allows the easy recovery and recycling of fluorous catalysts. This review focuses on fluorous biphasic catalysis. |
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| Keywords: | fluorous biphase system perfluorinated solvents phase behavior fluorous catalysts fluorous biphasic catalysis |
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