Preparation,proton transport properties and use in gas sensors of thin films of zirconium phosphate with γ-layered structure

Pellicular γ-zirconium phosphate (γ-ZP_(p)), i.e. sheets made up entirely of oriented lamellae of Zr(PO₄)(H₂PO₄)·2H₂O (γ-ZP), have been obtained by filtering colloidal dispersions of exfoliated γ-ZP in water/acetone. The ac-conductivity of γ-ZP_(p) and γ-ZP was measured in the temperature range 20/–20°C on samples previously conditioned at relative humidities between 90 and 5%. In both cases, the conductivity dependence on material hydration indicates the presence of a non-negligible bulk transport at low relative humidities. For each relative humidity the conductivity data have been parameterised on the basis of the Arrhenius equation. Activation energy and pre-exponential factor values suggest the presence of the same conduction mechanism in both materials. The conductivity of γ-ZP_(p) measured by applying the electric field parallel to the sheets ranges from 3·10⁻⁴ to 1·10⁻⁵ S cm⁻¹ for relative humidity decreasing from 90 to 11%, being an order of magnitude higher than that of γ-ZP. Since the pellicular and microcrystalline material have very similar surface areas (11–12 m²/g), the higher conductivity of γ-ZP_(p) is mainly due to the preferred particle orientation parallel to the electric field. Paper presented at the 3rd Euroconference on Solid State Ionics, Teulada, Sardinia, Italy, Sept. 15–22, 1996