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Synthesis, crystal structure, and characterizations of a (6,3)-connected coordination polymer based on cadmium(II) and nickel(II) |
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| Authors: | Z H Meng Z G Zhong X X Wang J L Zhao |
| Institution: | 1. College of Chemistry and Pharmacy Engineering, Nanyang Normal University, Nanyang, 473061, P.R. China 2. Center of Analytical and Testing, Nanyang Normal University, Nanyang, 473061, P.R. China 3. School of Material Science and Engineering, Hebei University of Technology, Tianji, 300130, P.R. China 4. School of Chemical Engineering and Technology, Hebei University of Technology, Tianjin, 300130, P.R. China |
| Abstract: | A novel heteronuclear coordination polymer Cd(1,3-μ-SCN)6Ni2(C2H8N2)2(H2O)2 (I) has been prepared and characterized by elemental analysis, EDS analysis, PXRD and IR spectrum and single-crystal X-ray diffraction. The single-crystal X-ray diffraction analysis revealed that compound I crystallizes in a monoclinic system of space group C2/m with a = 19.427(8), b = 9.622(3), c = 7.261(3) Å, β = 105.383(10)°. The compound exhibits a (6,3)-connected two-dimensional layer which is built up from the strict alternation of 6-connected {CdS6} octahedra and 3-connected {NiON5} octahedra. |
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