Fluoro-ketones VI. Synthesis of perfluoro di- and tetra-ketones from 1,1-dichlorobenzyllithium and perfluoroesters |
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| Authors: | Loomis S. Chen Christ Tamborski |
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| Affiliation: | Air Force Wright Aeronautical Laboratories, Materials Laboratory Wright-Patterson Air Force Base, Ohio 45433 U.S.A |
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| Abstract: | The reaction of C6H5CCl2Li with perfluorinated mono and diesters yields fluorochloroketones in high yield. Hydrolysis of such compounds produces alpha-beta fluorinated di- and tetra-ketones, respectively. Various hydrates of the fluorinated ketones have been identified. |
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