The reaction of arsenic pentafluoride with graphite fluorosulfate |
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| Authors: | S Karunanithy F Aubke |
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| Institution: | Department of Chemistry, The University of British Columbia, Vancouver, B.C. V6T 1Y6 Canada |
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| Abstract: | The reaction of graphite fluorosulfate with an excess of arsenic(V) fluoride produces the new intercalation compound C14+ AsF5(SO3F)]?. Identification as a first stage compound rests on the observed interlayer separation of 7.92 Å and the position of νE2g at 1636 cm?1 in the Raman spectrum. Evidence for AsF5(SO3F)]? as intercalant is based on 19F NMR spectra of the solid material. C14+AsF5(SO3F)]? is found to exhibit high electrical conductivities in the basal plane. |
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