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Synthesis and reactions of (E)-1,1,1-trifluoro-2-methyl-2-penten-4-ylidene-malonodinitrile
Authors:Janusz SepioŁ
Institution:Lehrstuhl für Anorganische Chemie II, Ruhr-Universität Bochum, Postfach 102148, D-4630 Bochum F.R.G.
Abstract:Condensation of (E)-1,1,1-trifluoro-2-methyl-2-penten-4-one with malonodinitrile affords mixtures of unsaturated nitriles. Attempted cyclization of these nitriles in concentrated sulfuric acid furnishes derivatives of alkylidenecyanoacetamides and alkylidenemalonodiamide.
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