Benzene carbon-hydrogen bond activation using Ru(C6Me6)[PH(C6H11(2]H2 |
| |
| Authors: | Robert H. Morris Mahmoud Shiralian |
| |
| Affiliation: | Department of Chemistry and the Scarborough Campus, University of Toronto, 80 St. George St., Toronto, Ontario, M5S 1A1 Canada |
| |
| Abstract: | The dihydride Ru(C6Me6)[PH(C6H11)2]H2 is synthesized in high yield by reducing Ru(C6Me6)[PH(C6H11)2]Cl2 with Na[AlH2(OCH2CH2OMe)2]. In benzene it loses hydrogen under UV irradiation to give Ru(C6Me6)[PH(C6H11(2]H(C6H5). |
| |
| Keywords: | Author to whom correspondence should be addressed. |
| 本文献已被 ScienceDirect 等数据库收录！ |
