Benzene carbon-hydrogen bond activation using Ru(C6Me6)[PH(C6H11(2]H2 |
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| Authors: | Robert H Morris Mahmoud Shiralian |
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| Institution: | Department of Chemistry and the Scarborough Campus, University of Toronto, 80 St. George St., Toronto, Ontario, M5S 1A1 Canada |
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| Abstract: | The dihydride Ru(C6Me6)PH(C6H11)2]H2 is synthesized in high yield by reducing Ru(C6Me6)PH(C6H11)2]Cl2 with NaAlH2(OCH2CH2OMe)2]. In benzene it loses hydrogen under UV irradiation to give Ru(C6Me6)PH(C6H11(2]H(C6H5). |
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| Keywords: | Author to whom correspondence should be addressed |
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