UV photoelectron spectra of some transition metal(II) acetylacetonates |
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| Authors: | Susumu Kitagawa Isao Morishima Kenichi Yoshikawa |
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| Institution: | Department of Chemistry, Kinki University, Higashi-Osaka 577, Japan;Department of Hydrocarbon Chemistry, Kyoto University, Kyoto 606, Japan;College of General Education, Tokushima University, Tokushima 770, Japan |
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| Abstract: | The He(I) photoelectron spectra of acetylacetone (HAA) and its metallo complexes, M(II)(AA)2 (M(II) = Mn, Co, Ni, Cu and Zn), have been measured. These spectra show characteristic metal-dependence, from which the assignment is made. The order of the orbital energy level, d > π3 > n? > n+, holds for all the complexes reported here. The splitting of these orbitals is found to depend on the central metal ion specifically. |
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| Keywords: | Author to whom correspondance should be addressed |
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