Synthesis of new mixed ligand complexes of copper(II) dithiocarbamates |
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Authors: | KKM Yusuff KMuhammad Basheer M Gopalan |
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Institution: | Department of Chemistry, Univereity of Calicut, Kerala, 673 635, India |
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Abstract: | New mixed ligand complexes of copper(II) dithiocarbamates of the general formula, CuCl(R2dtc)L] or CuCi(R′ dtc)L] (RCH3 or C2H5, R′ = (CH2)5, dtc =-NCSS? and L = Pyridine, 3-picoline or 4-picoline), have been prepared by the reaction of bis(dithiocarbamato)di-μ-chloro-dicopper(II) complexes with pyridine or picolines. The complexes are found to be non-electrolytes in nitrobenzene. Magnetic susceptibilities, i.r. and electronic spectra of the complexes are reported. A psuedo-tetrahedral structure is suggested for these complexes. |
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Keywords: | Author to whom all correspondence should be directed Present address: Department of Applied Chemistry University of Cochin Cochin 682 002 Kerala India |
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